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Does calcium react with EDTA?

Author

William Brown

Published Jun 18, 2026

Does calcium react with EDTA?

The method uses a very large molecule called EDTA which forms a complex with calcium ions. EDTA stands for ethylenediaminetetraacetic acid. As a result, when the calcium ion–PR complex is titrated with EDTA the Ca2+ ions react to form a stronger complex with the EDTA.

How do you calculate hardness from EDTA titration?

Use the standard EDTA solution to titrate the hard water….The Calculations

  1. The balanced chemical equation for the reaction between calcium and magnesium ions and EDTA is: Ca2+ + H2EDTA2- → CaEDTA2- + 2H+
  2. Moles of EDTA must be calculated using the results of the titration:

How does EDTA complex with Ca2+ and Mg2 +?

EDTA is short for ethylenediaminetetraacetic acid. For the titration, the sample solution containing the calcium and magnesium ions is reacted with an excess of EDTA. The indicator is added and remains blue as all the Ca2+ and Mg2+ ions present are complexed with the EDTA.

How many moles of EDTA react with Ca2+?

One mole
One mole of Ca2+ ions will react with one mole of EDTA ions.

How many mL of EDTA are needed to titrate the Ca2+ ion in the aliquot?

(c) How many moles of Ca2+ are in a 25.00 mL aliquot? ex. 25.00 mL aliquot from above example is titrated with EDTA. 32.83 mL of EDTA was required.

How does EDTA bind to calcium?

Disodium EDTA is a chelating agent used in studies involving calcium. The sodium ion of the chelate is displaced by calcium to form soluble, non-toxic physiologically unavailable complexes that are excreted through urine.

How do you calculate hardness from Mg and Ca?

The amount of hardness is expressed in milligrams per litre (mg/L) or grains per gallon (gpg) as calcium carbonate. Hardness is calculated from the equation Hardness = 2.497 (Ca) + 4.118 (Mg). Therefore, fluctuations in the magnesium pool affect hardness stronger than do calcium fluctuations.

How do you measure water hardness of calcium?

The value of calcium hardness as CaCO3 can always be obtained by multiplying the Ca2+ concentration by a factor of 100/40, or 2.5. Another common measurement of water hardness is known as total hardness as CaCO3. This measurement takes into account both Ca2+ and Mg2+ ions.

What is the molar ratio of EDTA to CaCO3?

Each mL EDTA used = 0.00002 equivalents: 0.001 L x 0.02 equivalent EDTA/L = 0.00002 equivalent EDTA = equivalent CaCO3. Each mL EDTA used = 0.00001 moles CaCO3:0.001 L x 0.01 mol EDTA/L = 0.00001 moles EDTA = moles Ca or CaCO3.

How do you calculate the hardness of CaCO3?

∴1L (1000ml) of given hard water = mg of CaCO3 eq. Total Hardness of water = 1000 V2/V1 mg/l = 1000 V2/V1 ppm.